Organic Metal Complex.II-III II. 10-Hydroxy-benzo-(h)-quinoline.
نویسندگان
چکیده
منابع مشابه
Zero Kinetic Energy Photoelectron Spectroscopy of Benzo[h]quinoline.
We report zero kinetic energy (ZEKE) photoelectron spectroscopy of benzo[h]quinoline (BhQ) via resonantly enhanced multiphoton ionization (REMPI) through the first electronically excited state S1. From the simulated REMPI spectra with and without Herzberg-Teller coupling, we conclude that vibronic coupling plays a minor but observable role in the electronic excitation to the S1 state. We furthe...
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Reactions of 10-benzo[h]quinolyllithium with a series of organosilanes led to the formation of neutral pentacoordinate complexes. The diethynyl-substituted complex was able to be converted to di(arylethynyl)-substituted ones by the Sonogashira-Hagihara coupling reaction. Electronegative substituents shortened N-Si distances and enhanced fluorescence intensity from the complexes.
متن کاملMutagenicity and tumorigenicity of dihydrodiols, diol epoxides, and other derivatives of benzo(f)quinoline and benzo(h)quinoline.
The mutagenic activities of benzo[f]quinoline, benzo[h]quinoline, and a number of their derivatives, including dihydrodiols, K-region oxides, diol epoxides, and tetrahydroepoxides, were assessed in strain TA 100 of Salmonella typhimurium. The dihydrodiol derivatives of benzo[f]quinoline and benzo[h]quinoline were also tested for tumorigenic activity in newborn mice. Benzo[f]quinoline was metabo...
متن کامل2-(Anthracen-9-yl)-10-methoxybenzo[h]quinoline acetone hemisolvate
The asymmetric unit of the title structure, C(28)H(19)NO·0.5C(3)H(6)O, comprises one 2-(anthracen-9-yl)-10-meth-oxy-benzo[h]-quinoline mol-ecule and an acteone mol-ecule with an occupany of 0.5. The solvent mol-ecule is disordered around a centre of symmetry. Its occupancy was determined from NMR data and kept fixed during the refinement. The two conjugated ring systems of the mol-ecule are alm...
متن کاملCrystal structures of dichloridopalladium(II), -platinum(II) and -rhodium(III) complexes containing 8-(diphenylphosphanyl)quinoline
The crystal structures of di-chlorido-palladium(II), -platinum(II) and -rhodium(III) complexes containing 8-(di-phenyl-phosphan-yl)quinoline, (SP-4)-[PdCl2(C21H16NP)], (1) [systematic name: di-chlor-ido-(8-di-phenyl-phosphanyl-quinoline)-palladium(II)], (SP-4)-[PtCl2(C21H16NP)]·CH2Cl2, (2) [systematic name: di-chlorido-(8-di-phenyl-phos-phanyl-quinoline)-platinum(II) dichlorometh-ane monosolvat...
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ژورنال
عنوان ژورنال: Nippon kagaku zassi
سال: 1957
ISSN: 0369-5387,2185-0917
DOI: 10.1246/nikkashi1948.78.108